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The block cipher Jarvis and the hash function Friday, both members of the MARVELlous family of cryptographic primitives, were recently proposed as custom designs aimed at addressing bottlenecks involv...
The ZK-STARK technology, published by Ben-Sasson et al. in ePrint 2018/046 is hailed by many as being a viable, efficient solution to the scaling problem of cryptocurrencies. In essence, a ZK-STARK pr...
Over the past decade, we have developed a spectroscopic approach to measure electric fields inside matter with high spatial (<1 Å) and field (<1 MV/cm) resolution. The approach hinges on exploiti...
The physical properties of solvents strongly affect the spectra of dissolved solutes, and this phenomenon can be exploited to gain insight into the solvent-solute interaction. The large solvatochromic...
Electric fields affect any process or transition that involves the movement of charge. Stark spectroscopy is a general term describing the study of spectral changes in the presence of electric fields,...
The charge redistribution upon photoexcitation is investigated for a series of pyrene photoacids to better understand the driving force behind excited-state proton-transfer processes. The changes in e...
Vibrational Stark effect spectroscopy was used to measure electrostatic fields in the hydrophobic region of the active site of human aldose reductase (hALR2). A new hALR2 inhibitor was designed and sy...
Many mixed-valence systems involve two or more states with different electric dipole moments whose magnitudes depend upon the charge transfer distance and the degree of delocalization; these systems c...
The vibrational Stark effect (VSE) has proven to be an effective method for the study of electric fields in proteins via the use of infrared probes. To explore the use of VSE in nucleic acids, we inve...
Stark and absorption spectra for the hole-transfer band of the bacteriochlorophyll special pair in the wild-type and L131LH, M160LH, and L131LH/M160LH mutants of the bacterial reaction center of Rhodo...
Stark spectra have been obtained in the region of absorption by the accessory bacteriochlorophylls (the B-band region around 800 nm) in Rhodobacter sphaeroides reaction centers. The Stark spectra in t...
Resonance Stark effects are nonclassical Stark effects associated with excited-state charge-transfer processes. The theory of resonance Stark effects developed in Part 2 of this series is generalized ...
The response of an intervalence band to an applied electric field, called an intervalence band Stark effect, is considered in detail. Because the application of an electric field to a symmetric mixed-...
Infrared spectroscopy is widely used to probe local environments and dynamics in proteins. The introduction of a unique vibration at a specific site of a protein or more complex assembly offers many a...
The Stark spectrum of the intervalence band of the special pair radical cation in bacterial photosynthetic reaction centers is presented. This spectrum, centered at 2600 cm-1, is modeled using a gener...

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