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为阐明煤在无氧环境下升温过程中CO的产生及变化规律,利用程序控制升温和时间分辨红外光谱分析方法,在无氧环境下对煤进行程序控制升温,采集并分析了煤无氧升温过程中CO产生及变化规律的时间分辨红外光谱谱图,揭示了煤无氧升温过程中CO的产生和变化规律,建立了描述CO生成量与煤质量分数之间函数关系的方程。结果表明:在30~370 ℃,由于热解温度不够高,无CO产生;在煤失重最快的370~650 ℃,CO生成...
Less than 10% of oil is usually recovered from liquid-rich shales and this leaves much room for improvement, while water injection into shale formation is virtually impossible because of the extremely...
采用等温热重法对比神木煤焦在900~1 050 ℃分别与CO 2和水蒸气气化的反应活性。为研究气化残炭反应性,分别采用均相模型、缩核模型、混合模型和修正体积模型对煤焦气化后期反应速率与碳转化率的关系进行拟合。结果表明:混合模型和修正体积模型对实验数据有很好的拟合效果;均相模型和缩核模型的拟合效果随气化温度和反应气氛而变化;不同模型预测煤焦分别与CO 2和水蒸气反应后期的活化能范围分别为200.65...
针对高瓦斯采空区漏风流内含有瓦斯的实际情况,自制了含瓦斯风流条件下煤的低温氧化实验系统,按拟定的配气方案开展了低温氧化实验,分析了CO的生成规律。结果表明:随氧气体积分数的降低或甲烷体积分数的升高,CO生成的初始温度滞后,相同温度时CO的生成量减小。因此,用新鲜空气来预测高瓦斯采空区的煤自燃状态,易造成错判、误判。根据气固多相反应动力学原理,分析了化学反应速率变化的原因,从而合理解释了实验结果。
New findings give further information on the mechanism of carbon monoxide selective oxidation over g-alumina supported nanoparticle sized gold catalysts. a) CO2 formation, increasing with rising t...
2% Au/Al2O3 catalysts were prepared by a novel method involving Direct Anionic Exchange (DAE). The method produces strong bonding of the gold complex (HAuCl4) to the alumina support with no loss of...
The development of a method for making an adherent coating of Au/TiO2 on a cordierite monolith is described. The optimum method entails first forming a wash-coat of TiO2 by combining a colloidal d...
A compact, internally heated, catalytic reactor is demonstrated for the low-temperature oxidation of carbon monoxide. Carbon nanofibres were grown on carbon felt and used as a support material for ...
Gold catalysts were prepared on TiO2 supports of different phase structures (i.e., anatase, rutile and biphasic), TiO2 crystal size (i.e., 9-23 nm), surface and textural properties (i.e., hydration...
Au-based catalysts, generally known for high activity in the selective catalytic oxidation of CO to CO2 at ambient temperatures, can play a significant role in increasing the fuel cell system’s CO ...
The catalytic activity of oxide-supported gold nanoparticles depends crucially on their size. The present work describes a dedicated set-up in which particle size is determined by grazing incidence...
Catalysts for low temperature CO oxidation were prepared by decorating hydroxyapatite (HAp) ceramic foam scaffolds with highly dispersed gold nanocrystals using a deposition-precipitation (DP) pro...
The interfacial interaction of gold nanoparticles deposited on either model SiO2/Si(100) or high surface area amorphous or mesoporous silica with minute amounts of promoter oxide like “active” FeO...

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