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Wavelength dependence of isotope fractionation in N2O photolysis
Wavelength dependence isotope fractionation N2O photolysis
2009/3/10
In previous reports on isotopic fractionation in the ultraviolet photolysis of nitrous oxide (N2O) only enrichments of heavy isotopes in the remaining N2O fraction have been found. However, most direc...
Atmospheric deuterium fractionation:HCHO and HCDO yields in the CH2DO + O2 reaction
Atmospheric deuterium fractionation HCHO HCDO yields CH2DO + O2 reaction
2008/12/25
The formation of formaldehyde via hydrogen atom transfer from the methoxy radical to molecular oxygen is a key step in the atmospheric photochemical oxidation of methane, and in the propagation of deu...
Hydrogen isotope fractionation in the photolysis of formaldehyde
Hydrogen isotope fractionation in the photolysis of formaldehyde
2008/10/31
Experiments investigating the isotopic fractionation in the formation of H2 by the photolysis of CH2O under tropospheric conditions are reported and discussed. The deuterium (D) depletion in the H2 pr...