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双核Pt(Ⅳ)配合物与Guanosine-5′-Monophosphate和Glutathione反应的核磁共振光谱研究(英文)
抗肿瘤试剂 双核铂(Ⅳ)配合物 DNA Guanosine-5′-Monophosphate(5′-GMP) Glutathione(GSH)
2008/3/20
合成了一个新型的双核Pt(Ⅳ)配合物{[cis-Pt(NH3)2Cl(OH)2]2(4,4′-methylenedianiline)}(NO3)2(化合物1)及相应的 15N标记化合物{[cis-Pt( 15NH3)2Cl(OH)2]2 (4,4′-methylenedianiline)}(NO3)2(化合物 15N-1)。利用 1H NMR和ESMS进行了结构表征，化合物 15N-1的2D[ 1...
Rapid Complexometric Determination of Mercury(II) Using Glutathione as a Selective Demasking Reagent
Complexometry Demasking reagent EDTA titration Glutathione Mercury determination
2010/4/20
A simple, rapid and selective complexometric method is proposed for the determination of mercury(II) in the presence of associated metal ions. Mercury(II) is first complexed with an excess of EDTA and...