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An implicit asymptotic-preserving and energy-charge conserving (APECC) Particle-In-Cell method is proposed to solve the Vlasov-Maxwell (VM) equations in the quasi-neutral limit. Charge conservation is...
This week William Nordhaus, Sterling Professor of Economics at Yale, won the Nobel Prize. At the Yale School of Forestry & Environmental Studies, where he holds a secondary appointment, his research a...
Slow, ~50 ps, P* → P(+)HA(-) electron transfer is observed in Rhodobacter capsulatus reaction centers (RCs) bearing the native Tyr residue at M208 and the single amino acid change of isoleucine at M20...
The short-lived (<1 ps) initial intermediate state P(+)B(L)(-) in the photoinduced charge separation process of the bacterial photosynthetic reaction center has been trapped in two D(LL)-based Rhodoba...
The charge redistribution upon photoexcitation is investigated for a series of pyrene photoacids to better understand the driving force behind excited-state proton-transfer processes. The changes in e...
Stark and absorption spectra for the hole-transfer band of the bacteriochlorophyll special pair in the wild-type and L131LH, M160LH, and L131LH/M160LH mutants of the bacterial reaction center of Rhodo...
The triplet state of aromatic molecules forms and decays by intersystem crossing, as originally demonstrated by Kasha and Lewis. By contrast, the triplet state of the primary electron donor, 3 P, in p...
A thermodynamic model describing multicomponent fluid membranes under the influence of lateral forces due to a buried charge is developed to estimate the magnitude and dynamics of field-induced latera...
We report the Stark spectra of the Soret, Q, and charge-transfer bands of deoxymyoglobin. The data show that band III has charge-transfer character but that the magnitude of the charge displacement is...
The electronic absorption spectrum of the homodimeric special pair in bacterial photosynthetic reaction centers is greatly modified when one of the bacteriochlorophylls is replaced by a bacteriopheoph...
The rates of electron-transfer reactions can be systematically varied by application of external electric fields. The electric field effect on the charge recombination rate constant of the state P[sup...
Photochemical hole-burning spectra have been obtained for the lowest energy electronic absorption band of the primary electron donor P of photosynthetic reaction centers (RCs) that exhibit different r...
A general method is demonstrated for experimentally obtaining the rate constant of electron transfer as a function of the free energy of the reaction in nonoriented systems. An external electric field...
The triplet state of the primary electron donor is formed in bacterial reaction centers when electron transfer to the quinone is blocked. The relative quantum yield of formation and the rate of decay ...

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