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Microbiologic reduction of synthetic and geologic Fe31 oxides associated with four Pleis-tocene-age, Atlantic coastal plain sediments was investigated using a dissimilatory Fe reducing bacterium ( She...
Abstract: A theoretical model describing the interaction between crystalline swelling and cation exchange selectivity is proposed for expanding 2:1 phyllosilicates. The model is based on the assumptio...
SinglecrystalsofnaturalF-richapatiteand800keVKr ion-beam¤Camorphizedapatit wereirradiatedbyanelectronbeaminatransmissionelectronmicroscopeoverarange ofbeamenergiesandbeamcurrents.Irradiationofcrysta...
Manycrystallinesolidshavemultiplenonequivalentsitesamongwhichdifferentatoms showsubstitutionallong-rangeorder-disorderphenomena.Theorder-disorderkineticsof anatomamongany n nonequivalentsitesinacrys...
High-temperature volumes of K-Na mixing have been investigated for a seven-member low albite-microcline ion-exchange series by conducting X-ray powder diffraction mea- surements from room temperatur...
A macroscopic energy balance model for crystalline swelling of 2:1 phyllosilicates is presented. Crystalline swelling for a static system is modeled by a balance among the potential energies of attrac...
The basal spacing of a set of smectites, with layer charges between 0.74 and 1.14 electrons per unit cell, have been measured while the smectites were in equilibrium with NaCl solutions having concent...
The dissolution behavior of five noncrystalline oxides, montmorillonite, kaolinite, chlorite, and sepiolite in a basic tiron solution was studied at pH 10.5 and 80°C. The results show that for montmor...
Abstract: At pH 12 Co-ferrihydrite transformed to either Co-goethite or Co-magnetite, the latter compound appearing at Co additions of > 18 mole %. Although Co was readily taken up by the magnetite st...
The resolution of the infrared spectra of structural OH in kaolin-group minerals increases with decreasing temperature. Poorly crystalline kaolinite gives typical infrared spectra, which suggest the e...
The capabilities of X-ray powder diffraction (XRD), infrared absorption (IR), solid-state magic-angle-spinning nuclear magnetic resonance (MAS-NMR), and chemical dissolution methods were assessed for ...
Atmospheric acidic deposition introduces hydrogen ions to terrestrial and aquatic ecosystems, which become partially neutralized by chemical weathering. In the southern Alps of Switzerland, small catc...
Al-substituted goethites were prepared by rapid oxidation of mixed FeCl2-AlCl3 solutions at pH 6.8 in the presence of CO2 at 25亱C. A combination of Al substitution and adsorption of CO2 reduced crysta...
A series of mixed iron and titanium oxide coprecipitates ranging in composition between 0 < Ti/Ti + Fe < 1 was synthesized and aged under varying conditions of pH, temperature and time in order to est...
Sesquioxidic soil clays from Oxisols in South Africa, Australia and Brazil, and two clays from Andosols in Japan and New Zealand, were investigated by selective dissolution techniques. Acid ammonium o...

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