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Abstract: Samples containing illite and illite-smectite, having different crystal shapes (plates, “barrels”, and filaments), were selected for sorption experiments with cesium. There is a positive cor...
Abstract: The uptake of Sr and Cs by 2 types of aluminum pillared layered clays (Al-PILC), a reference sample (AZA) and a specially tailored sample (FRAZA), were investigated. The AZA sample was prepa...
Sorption parameters are important components of models used to predict mass transport through dense or compacted earthen materials. These parameters are, however, generally determined in batch tests w...
Batch cation-exchange experiments were performed on chlorite, using synthetic ground water containing cesium in the concentration range 10−9–10−3 M. The sorption behavior was complex; with...
Ion-exchange sites with very high selectivity for Cs ( ΔG Ca 2+ Cs + = 40 kJ/eq) similar to illite were generated in a controlled way in montmorillonites by (1) repeated wetting-drying cycles and by (...
The immobilization of soluble Cs from spent fuel elements by ion exchange and direct chemical reaction with clay minerals or shales was investigated under hydrothermal conditions. Various clay mineral...
Seven kaolins from Georgia (southeastern U.S.A.), ranging from high to low commercial grade, were characterized by X-ray powder diffraction and chemical techniques to establish that the variation in q...
The effects of hydrothermal conditions on the sorption and fixation of cesium by various clay minerals and shales were investigated. Hydrothermal heating, which may be expected in a radioactive waste ...
The use of electron diffraction contrast to detect local concentrations of interlayer cations in mica-vermiculites was examined. Cs and Mg, because of their contrasting atomic scattering amplitudes fo...
Abstract: Selectivity of a number of vermiculites, montmorillonites and micas for K and Cs ions was determined by sorption of these ions from equilibrium solutions of diverse concentrations. The selec...

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