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We examine the co-variations of tropospheric water vapor, its isotopic composition and cloud types and relate these distributions to tropospheric mixing and distillation models using satellite observa...
The project CARIBIC (http://caribic-atmospheric.com) aims to study atmospheric chemistry and transport by regularly measuring many compounds in the free troposphere and the upper troposphere/lowermost...
Formaldehyde of known, near-natural isotopic composition was photolyzed in the SAPHIR atmosphere simulation chamber under ambient conditions. The isotopic composition of the product H2 was used to det...
The pressure dependence of the relative photolysis rate of HCHO vs. HCDO has been investigated for the first time, using a photochemical reactor at the University of Copenhagen. The dissociation of HC...
Water plays a major role in the chemistry and radiative budget of the stratosphere. Air enters the stratosphere predominantly in the tropics, where the very low temperatures around the tropopause cons...
The sensitivity of terrestrial environments to past changes in heat transport is expected to be manifested in Holocene climate proxy records on millennial to seasonal timescales. Stalagmite formation...
Dansgaard-Oeschger events occurred frequently during Marine Isotope Stage 3 (MIS3), as opposed to the following MIS2 period, which included the Last Glacial Maximum (LGM). Transient climate model sim...
The nitrogen (δ15N) and triple oxygen (δ17O and δ18O) isotopic composition of nitrate (NO3−) was measured year-round in the atmosphere and snow pits at Dome C, Antarctica (DC, 75.1° S, 123.3° E)...
The isotopic composition of molecular hydrogen (H2) produced by photochemical oxidation of methane (CH4) and Volatile Organic Compounds (VOCs) is a key quantity in the global isotope budget of (H2). T...
The uptake of HNO3 to deliquescent airborne sea-salt particles (RH = 55%, P = 760 torr, T = 300 K) at concentrations from 2 to 575 ppbv is measured in an aerosol flow tube using 13N as a tracer. Small...
In previous reports on isotopic fractionation in the ultraviolet photolysis of nitrous oxide (N2O) only enrichments of heavy isotopes in the remaining N2O fraction have been found. However, most direc...
Atmospheric chloromethane (CH3Cl) plays an important role in stratospheric ozone destruction, but many uncertainties still exist regarding strengths of both sources and sinks and the processes leading...
The kinetic isotope effects in the reactions of CH3Cl, 13CH3Cl and CD3Cl with OH radicals and Cl atoms were studied in relative rate experiments at 298±2 K and 1013±10 mbar. The reactions were carried...
We report the first high-precision measurements of δ 18O and Δ 17O at high southern latitudes that can resolve changes in the isotopic composition of water vapor in the lowermost stratosphere and uppe...
A historical record of changes in the N2O isotope composition is important for a better understanding of the global N2O atmospheric budget. Here we have combined measurements of trapped gases in the f...

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