搜索结果: 1-5 共查到“有机化学 solvent-free”相关记录5条 . 查询时间(0.101 秒)
An efficient one-pot synthesis of dihydropyrimidinones catalyzed by zirconium hydrogen phosphate under solvent-free conditions
Biginelli reaction solvent-free zirconium hydrogen phosphate
2010/10/18
A simple, efficient, and practical procedure for the Biginelli reaction using zirconium hydrogen phosphate [Zr(H2PO4)2] as a novel solid acid catalyst is described under solvent-free conditions in hig...
H2{SO}4-silica as an efficient and chemoselective catalyst for the synthesis of acylal from aldehydes under solvent-free conditions
Acylals aldehydes catalysis solvent-free reactions
2010/4/9
A variety of aldehydes react with acetic anhydride in the presence of a catalytic amount of H2SO4-silica to afford the corresponding 1,1-diacetates (acylals) in excellent yields. Ketones are not affec...
High Yielding Oxidative Deprotection of Silyl and Pyranyl Ethers to Their Corresponding Carbonyl Compounds with Strontium Manganate in the Presence of Aluminium Chloride in Solution and Under Solvent-Free Conditions
Strontium manganate aluminium chloride solvent-free conditions oxidative deprotection tetrahydropyranyl ethers
2010/4/13
Strontium manganate (SrMnO4) in the presence of aluminium chloride (AlCl3) is an efficient reagent for the high yielding oxidative deprotection of aromatic and aliphatic silyl and pyranyl ethers into ...
A Convenient and Efficient Synthesis of N-Acylsulfonamides in the Presence of Silica Phosphoric Acid under Heterogeneous and Solvent-Free Conditions
N-acylsulfonamide solvent-free silica phosphoric acid heterogeneous condition N-acylation
2010/4/8
Reaction of sulfonamides with carboxylic acid anhydrides and chlorides in the presence of silica phosphoric acid provided N-acyl sulfonamides in good to high yields. All reactions were performed under...
Solvent-Free Preparation of Primary Carbamates
Solvent-free N-unsubstituted carbamates isocyanic acid compounds containing hydroxyl group
2010/4/19
Herein, we describe a simple and efficient method for the conversion of compounds containing a hydroxyl group to primary carbamates at room temperature with excellent yield and purity, and without any...